Charge neutrality in epitaxial graphene on 6H-SiC(0001) via nitrogen intercalation

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DOI Доступ к ресурсу на сайте издателя			10.1103/PhysRevB.92.081409

Title: Charge neutrality in epitaxial graphene on 6H-SiC(0001) via nitrogen intercalation
Creator: Caffrey, Nuala M.
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Yakimova, Rositsa
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Abrikosov, Igor A.
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Armiento, Rickard
Date: 2015
DOI: 10.1103/PhysRevB.92.081409
Description: The electronic properties of epitaxial graphene grown on SiC(0001) are known to be impaired relative to those of freestanding graphene. This is due to the formation of a carbon buffer layer between the graphene layers and the substrate, which causes the graphene layers to become strongly n-doped. Charge neutrality can be achieved by completely passivating the dangling bonds of the clean SiC surface using atomic intercalation. So far, only one element, hydrogen, has been identified as a promising candidate. We show, using first-principles density functional calculations, how it can also be accomplished via the growth of a thin layer of silicon nitride on the SiC surface. The subsequently grown graphene layers display the electronic properties associated with charge neutral graphene. We show that the surface energy of this structure is considerably lower than that of others with intercalated atomic nitrogen and determine how its stability depends on the N2 chemical potential.

Created: 24-04-2018

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Публикации ТГУ Charge neutrality in epitaxial graphene on 6H-SiC(0001) via nitrogen intercalation