Accumulation of arsenic implantation-induced donor defects in heteroepitaxial Hg1−xCdxTe structures with the composition of the active layer xa = 0.30 was studied with the use of the Hall-efect measurements and mobility spectrum analysis. The studies allowed for identifying the carriers in the implantation-damaged n+-layer, namely, electrons with low and intermediate mobility, and for establishing the dependence of their concentration on the ion fuence. The electrically active implantation-induced defects in the studied structures, similar to the case of those with xa = 0.22, were identifed as atoms of interstitial mercury captured by dislocation loops and quasi-point defects. In the material with xa = 0.30, a weak dependence of theconcentration of low-mobility electrons on the fuence was observed. In general, a substantial diference in the properties of p+–n junctions formed as a result of arsenic implantation in the structures with xa = 0.30 and xa = 0.22 was established. The diference was explained by the efect of the graded-gap surface layer on the difusion of charged defects released during the implantation.