Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)

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Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)	7 MB	Adobe Acrobat PDF	Read	Download
DOI Доступ к ресурсу на сайте издателя			10.1021/acs.inorgchem.2c00596

Title: Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)
Creator: Kuznetsov, Artem B.
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Kokh, Konstantin A.
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Sagatov, Nursultan
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Gavryushkin, Pavel N.
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Molokeev, Maxim S.
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Svetlichnyi, Valerii A.
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Lapin, Ivan N.
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Kononova, Nadezda G.
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Shevchenko, Vyacheslav S.
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Bolatov, Asset
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Uralbekov, Bolat
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Goreiavcheva, Anastasia A.
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Kokh, Alexander E.
Date: 2022
DOI: 10.1021/acs.inorgchem.2c00596
Description: NaSrR(BO3)2(R = Ho-Lu, Y, Sc) compounds were obtained for the first time. Their structures exhibit disordered positions of Sr2+and Na+ atoms while RO6polyhedra are connected through the BO3 groups. Large distances between R atoms and high transparency in the range of 250-900 nm make them promising for phosphor applications. A pathway to obtain single crystals was shown by growing NaSrY(BO3)2and NaSrYb-(BO3)2by the top seeded solution growth method with Na2O-B2O3-NaFflux.

Created: 16-06-2023

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Физический факультет Synthesis and growth of rare earth borates NaSrR(BO3)2 (R = Ho− Lu, Y, Sc)