https://vital.lib.tsu.ru/vital/access/manager/Index ${session.getAttribute("locale")} 5 https://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000616152 Wed 29 Nov 2017 15:03:13 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000891838 Wed 13 Apr 2022 09:52:36 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000895623 Wed 08 Jun 2022 13:43:00 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000615952 Tue 28 Nov 2017 10:28:01 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000996392 Tue 14 Feb 2023 15:56:44 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000996394 Tue 14 Feb 2023 15:49:40 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000577223 Tue 13 Jun 2017 16:02:16 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000794662 Tue 09 Mar 2021 13:25:37 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000624644 season > watershed size. The effect of the latitude was minimal in spring for most TE but highly visible for Sr, Mo, Sb and U. The main factors controlling the shift of river feeding from surface and subsurface flow to deep underground flow in the permafrost-bearing zone were the depth of the active (unfrozen) seasonal layer and its position in organic or mineral horizons of the soil profile. In the permafrost-free zone, the relative role of carbonate mineral-bearing base rock feeding vs. bog water feeding determined the pattern of trace element concentration and fluxes in rivers of various size as a function of season. Comparison of obtained TE fluxes in WSL rivers with those of other subarctic rivers demonstrated reasonable agreement for most trace elements; the lithology of base rocks was the major factor controlling the magnitude of TE fluxes. The climate change in western Siberia and permafrost boundary migration will affect essentially the elements controlled by underground water feeding (DIC, alkaline-earth elements (Ca, Sr), oxyanions (Mo, Sb, As) and U). The thickening of the active layer may increase the export of trivalent and tetravalent hydrolysates in the form of organo-ferric colloids. Plant litter-originated divalent metals present as organic complexes may be retained via adsorption on mineral horizon. However, due to various counterbalanced processes controlling element source and sinks in plants – peat – mineral soil – river systems, the overall impact of the permafrost thaw on TE export from the land to the ocean may be smaller than that foreseen by merely active layer thickening and permafrost boundary shift.]]> Thu 03 May 2018 16:49:28 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000702740 Thu 02 Sep 2021 14:31:54 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001017252 Mon 22 Jan 2024 09:38:56 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:000925495 Mon 19 Dec 2022 15:45:40 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000528604 summer>autumn>winter. The ice formation in October included several stages: first, surface layer freezing followed by crack (fissure) formation with unfrozen water from the deeper layers spreading over the ice surface. This water was subsequently frozen and formed layered ice rich in organic matter. As a result, the DOC and metal (Mn, Fe, Ni, Cu, Zn, As, Ba and Pb) concentrations were highest near the surface of the ice column (0 to 20 cm) and decreased by a factor of 2 towards the bottom. The main implications of discovered freeze-driven solute concentrations in thermokarst lake waters are enhanced colloidal coagulation and removal of dissolved organic matter and associated insoluble metals from the water column to the sediments. The measured distribution coefficients of a TE between amorphous organo-ferric coagulates and lake water (<0.45 μm) were similar to those reported earlier for Fe-rich colloids and low molecular weight (<1 kDa, or <1–2 nm) fractions of thermokarst lake waters, suggesting massive coprecipitation of TE with amorphous Fe oxyhydroxide stabilized by organic matter. Although the concentration of most elements was lowest in spring, this period of maximal water coverage of land created a significant reservoir of DOC and soluble metals in the water column that can be easily mobilized to the hydrological network. The highest DOC concentration observed in the smallest (<100m2) water bodies in spring suggests their strongly heterotrophic status and, therefore, a potentially elevated CO2 flux from the lake surface to the atmosphere.]]> Mon 10 Dec 2018 12:52:19 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/koha:001016321 Fri 22 Dec 2023 14:15:38 KRAT ]]> https://vital.lib.tsu.ru/vital/access/manager/Repository/vtls:000494804 Fri 14 Dec 2018 09:43:00 KRAT ]]>