In our paper we report about the optical properties of diamonds having applied sense. Radiation destruction manifests itself in the form of absorption bands and luminescence of vacancies and interstitials. The charge state of the NV centers depends on the impurity-defective composition of the sample. Accelerated particles lose their energy to Cherenkov radiation. The fine splitting of the free exciton state affects the absorption and luminescence spectra in the recombination bands of free excitons and their condensed state