The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2 catalyst has been studied using a gas flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane ~ isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons.
Catalysis letters. 2017. Vol. 147, № 2. P. 310-317
Language
eng
582 Visitors580 Hits5 Downloads
Химический факультет
Oxidative dehydrogenation of 1-butene to 1,3-butadiene over a multicomponent bismuth molybdate catalyst: influence of c3–c4 hydrocarbons