High resolution infrared spectra of 17O enriched ozone isotopic species in the 5 µm range: The ν1 + ν3 bands of 17O3, 17O16O17O, 16O17O17O and 17O17O18O
In a mixture of 18 isotopic species of ozone including 17O, 16O and 18O oxygen atoms, four ν1+ν3 bands of 17O3, 17O17O18O, 16O17O17O, 17O16O17O in the 5 µm range are analyzed for the first time. The analyses, accounting for interactions between (101) with (002) and (200) states permitted to assign respectively 747 transitions for 17O17O18O, 705 transitions for 17O16O17O, 889 transitions for 16O17O17O and 1404 transitions for 17O3. The results of fits of effective Hamiltonian and transition moment parameters permit reproducing observed transitions within experimental accuracy. They allow to calculate synthetic spectra in excellent agreement with the observed ones. The band centers and rotational constants derived from experimental spectra are in good agreement with recent theoretical predictions from potential energy surfaces.
Journal of Quantitative Spectroscopy and Radiative Transfer. 2019. Vol. 232. P. 116-125
Language
eng
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High resolution infrared spectra of 17O enriched ozone isotopic species in the 5 µm range: The ν1 + ν3 bands of 17O3, 17O16O17O, 16O17O17O and 17O17O18O